Aarden F.B.'s Adsorption onto Heterogeneous Porous Materials: Equilibria PDF

By Aarden F.B.

ISBN-10: 9038628226

ISBN-13: 9789038628226

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Extra info for Adsorption onto Heterogeneous Porous Materials: Equilibria and Kinetics

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3-2 (squares). From high temperatures, evidence was found for stable multi-layer solutions at lower temperatures. 3-5b. No attempt was made to calculate those solutions. In the literature, such stable multi-layer solutions are usually never mentioned or investigated. 95*Told. Not only the estimate for the third starting point was found from calculations at higher temperature. This also accounted for the starting points from high and low bulk densities. After completion of the isotherms for one pore size, at all chosen temperatures, the calculation for the next pore size was started.

Z x w Fig. 4-1 Schematic representation of a slit-pore with pore-width w, and molecular diameter σ. Also consider a function fx , which is only a function of the direction x, perpendicular to the pore wall and a function fr, only a function of the distance from point r. 4-12) The external potential is the pore wall potential, calculated with Steele’s formula [Steele, 1973], which describes the interaction between the solid pore wall and the fluid component i. The solid density ρw is assumed to be uniform over planar sheets of atoms spaced ∆ apart .

3-2 Bulk liquid-liquid phase diagram for cases 3, 4 and 6. 8 Fig. 3-3 Bulk liquid-liquid phase diagram for case 5. 0 -14 -12 -10 -8 -6 -4 -2 0 * T ln( ρ/ ρs ) [-] Fig. 3-4 Case 1. Sorption isotherms at 3 different temperatures and 4 pore widths. 48 molecular diameters. 0 -12 -10 -8 -6 -4 -2 0 * T ln( ρ/ ρs ) [-] Fig. 3-5 Case 2. Sorption isotherms at 3 different temperatures and 4 pore widths. 48 molecular diameters. 0 -6 -4 -2 0 * T ln( ρ/ ρs ) [-] Fig. 3-6 Case 3. Sorption isotherms at 3 different temperatures and 4 pore widths.

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Adsorption onto Heterogeneous Porous Materials: Equilibria and Kinetics by Aarden F.B.


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